85127-62-4Relevant academic research and scientific papers
Regioselective Aziridine Ring Expansions
Clough, Stuart C.,Solomon, Robert,Crews, Elain,Jaques, Larry,Johnson, Ashby,Forehand, John
, p. 1489 - 1491 (2007/10/02)
1-Phenylmethyl-2-hydroxymethylaziridine (1) undergoes regioselective reactions with carbon disulfide to form thiazolidinethiones.Deuterium labeling experiments suggest that the reaction proceeds exclusively via aziridinium ring expansion.The regiospecificity appears to be electronically controlled.
