851387-15-0

Basic information

• Product Name: (S)-1-{(4R,5S)-5-[(R)-((R)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-hydroxy-methyl]-2,2-dimethyl-[1,3]dioxolan-4-yl}-5-(4-methoxy-benzyloxy)-pent-2-yn-1-ol
• Synonyms: (S)-1-{(4R,5S)-5-[(R)-((R)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-hydroxy-methyl]-2,2-dimethyl-[1,3]dioxolan-4-yl}-5-(4-methoxy-benzyloxy)-pent-2-yn-1-ol
• CAS NO: 851387-15-0
• Molecular Weight: 450.529
• Mol File: 851387-15-0.mol

Chemical Properties

• CAS DataBase Reference: (S)-1-{(4R,5S)-5-[(R)-((R)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-hydroxy-methyl]-2,2-dimethyl-[1,3]dioxolan-4-yl}-5-(4-methoxy-benzyloxy)-pent-2-yn-1-ol(CAS DataBase Reference)
• NIST Chemistry Reference: (S)-1-{(4R,5S)-5-[(R)-((R)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-hydroxy-methyl]-2,2-dimethyl-[1,3]dioxolan-4-yl}-5-(4-methoxy-benzyloxy)-pent-2-yn-1-ol(851387-15-0)
• EPA Substance Registry System: (S)-1-{(4R,5S)-5-[(R)-((R)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-hydroxy-methyl]-2,2-dimethyl-[1,3]dioxolan-4-yl}-5-(4-methoxy-benzyloxy)-pent-2-yn-1-ol(851387-15-0)

Safety Data

• Hazardous Substances Data: 851387-15-0(Hazardous Substances Data)

Upstream product

• 7757-38-2 2,3,5,6-di-O-isopropylidene-D-mannofuranose 
• 218434-90-3 1-but-3-ynyloxymethyl-4-methoxy-benzene 

Downstream Products

• 851387-23-0 4-(N,O-bis(phenoxycarbonyl)hydroxylamino)butyn-1-yl 2,3-O-isopropylidene-5-O-(4-fluorophenyl)-α-D-lyxo-furanoside 
• 851387-20-7 4-(4-methoxybenzyloxy)butyn-1-yl 2,3-O-isopropylidene-5-O-(p-toluenesulfonyl)-α-D-lyxo-furanoside 
• 851387-21-8 4-(4-methoxybenzyloxy)butyn-1-yl 2,3-O-isopropylidene-5-O-(4-fluorophenyl)-α-D-lyxo-furanoside 
• 851387-24-1 4-(N-hydroxylureidyl)butyn-1-yl 2,3-O-isopropylidene-5-O-(4-fluorophenyl)-α-D-lyxo-furanoside 
• 851387-17-2 4-(4-methoxybenzyloxy)butyn-1-yl 2,3-O-isopropylidene-α-D-mannofuranoside 
• 851387-19-4 4-(4-methoxybenzyloxy)butyn-1-yl 2,3-O-isopropylidene-α-D-lyxo-furanoside 
• 851387-22-9 4-hydroxybutyn-1-yl 2,3-O-isopropylidene-5-O-(4-fluorophenyl)-α-D-lyxo-furanoside 
• 851387-18-3 4-(4-methoxybenzyloxy)butyn-1-yl 2,3-O-isopropylidene-α-D-lyxo-pentanedialdo-1,4-furanoside 
• 851387-16-1 4-(4-methoxybenzyloxy)butyn-1-yl 2,3:5,6-di-O-isopropylidene-α-D-mannofuranoside 

Relevant articles and documents

Stereoselective synthesis of (2R,3S,4S,5R)-trans-3,4-dihydroxy-5-(4- fluorophenoxymethyl)-2-(1-N-hydroxyureidyl-3-butyn-4-yl)tetrahydrofuran and (2R,3S,4S,5R)-trans-5-ethynyl-2-(4-fluorophenoxymethyl)-3,4-O-isopropylidene tetrahydrofuran from mannose diac

Stereoselective synthesis of pharmaceutically interesting chiral tetrahydrofurans starting from mannose diacetonide is reported. A 1,4-diol system derived from mannose diacetonide, through a Mitsunobu reaction was stereospecifically cyclized to give chira