851487-22-4Relevant academic research and scientific papers
Stereoselective synthesis of δ-amino-β′-hydroxy-β, γ-unsaturated esters by the samarium(II) iodide-mediated aldol reaction of aldehydes with γ,δ-aziridiny-α,β-unsaturated esters
Ogawa, Yasuyuki,Kuroda, Kiichi,Mukaiyama, Teruaki
, p. 372 - 373 (2005)
δ-Amino-β′-hydroxy-β,γ-unsaturated esters were stereoselectively synthesized by the aldol reaction of aldehydes with samarium enolates generated by aziridine-fragmentation of γ,δ-aziridinyl- α,β-unsaturated esters using two moles of samarium(II) iodide. C
Highly stereoselective samarium(II) iodide-mediated aldol reactions of acylaziridines with aldehydes
Ogawa, Yasuyuki,Kuroda, Kiichi,Mukaiyama, Teruaki
, p. 1309 - 1333 (2007/10/03)
The samarium(II) iodide-mediated stereoselective aldol reactions of acylaziridines with aldehydes are described. β-Amino-β′-hydroxy ketones were synthesized in high yields by the aldol reaction of aldehydes with samarium enolates generated by aziridine-fr
