851530-57-9

Basic information

• Product Name: Bis(2,2-dimethylpropanoato)(4-methylphenyl)bis[tris[4-(trifluoromethyl)phenyl]phosphine]rhodium
• Synonyms: Bis(2,2-dimethylpropanoato)(4-methylphenyl)bis[tris[4-(trifluoromethyl)phenyl]phosphine]rhodium
• CAS NO: 851530-57-9
• Molecular Formula: C₅₉H₄₉F₁₈O₄P₂Rh
• Molecular Weight: 1328.85
• Product Categories: Catalysis and Inorganic Chemistry;Chemical Synthesis;Rhodium
• Mol File: 851530-57-9.mol
• Article Data: 1

Chemical Properties

• Melting Point: 204-206 °C
• Appearance: /
• CAS DataBase Reference: Bis(2,2-dimethylpropanoato)(4-methylphenyl)bis[tris[4-(trifluoromethyl)phenyl]phosphine]rhodium(CAS DataBase Reference)
• NIST Chemistry Reference: Bis(2,2-dimethylpropanoato)(4-methylphenyl)bis[tris[4-(trifluoromethyl)phenyl]phosphine]rhodium(851530-57-9)
• EPA Substance Registry System: Bis(2,2-dimethylpropanoato)(4-methylphenyl)bis[tris[4-(trifluoromethyl)phenyl]phosphine]rhodium(851530-57-9)

Safety Data

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26
• WGK Germany: 3
• Hazardous Substances Data: 851530-57-9(Hazardous Substances Data)

Usage

Description

Bis(2,2-dimethylpropanoato)(4-methylphenyl)bis[tris[4-(trifluoromethyl)phenyl]phosphine]rhodium is a complex chemical compound that contains rhodium as its central metal atom. Bis(2,2-dimethylpropanoato)(4-methylphenyl)bis[tris[4-(trifluoromethyl)phenyl]phosphine]rhodium also includes two ligands of 2,2-dimethylpropanoato and a 4-methylphenyl, as well as a bis(tris[4-(trifluoromethyl)phenyl]phosphine) group. It is known for its unique reactivity and stability, which makes it a promising candidate for use in various organic synthesis reactions.

Uses

Used in Organic Synthesis:
Bis(2,2-dimethylpropanoato)(4-methylphenyl)bis[tris[4-(trifluoromethyl)phenyl]phosphine]rhodium is used as a catalyst for various organic synthesis reactions. Its unique structure and properties allow it to facilitate a wide range of reactions in the field of organic chemistry, making it a valuable tool for chemists.
Used in Pharmaceutical Industry:
In the pharmaceutical industry, Bis(2,2-dimethylpropanoato)(4-methylphenyl)bis[tris[4-(trifluoromethyl)phenyl]phosphine]rhodium is used as a catalyst for the synthesis of complex organic molecules, including those used in the development of new drugs. Its ability to catalyze a variety of reactions makes it a versatile and essential component in the synthesis of pharmaceutical compounds.
Used in Chemical Research:
Bis(2,2-dimethylpropanoato)(4-methylphenyl)bis[tris[4-(trifluoromethyl)phenyl]phosphine]rhodium is also used in chemical research as a catalyst for studying reaction mechanisms and exploring new synthetic pathways. Its unique reactivity and stability make it an ideal candidate for investigating novel reactions and understanding the underlying chemistry.

Upstream product

• 63902-12-5 [RhCl(cis-cyclooctene)2]2 
• 624-31-7 4-tolyl iodide 
• 13406-29-6 tris(para-trifluoromethyl)phenyl phosphine 

Relevant articles and documents

Direct C-arylation of free (NH)-indoles and pyrroles catalyzed by Ar-Rh(III) complexes assembled in situ

Ar-Rh(III) pivalate complexes assembled in situ from the reaction of [RhCl(coe)2]2 (coe = cis-cyclooctene), [p-(CF3)C6H4]3P, and CsOPiv effectively catalyzed the direct C-arylation of free (NH)-indoles and (NH)-pyrroles in good yields and with high regioselectivity. The reaction displayed excellent functional group compatibility and low moisture sensitivity. Kinetics studies support a mechanism involving phosphine displacement by indole in complex 2 (resting state of the catalyst), followed by a rate-limiting C-H bond metalation. Copyright