85157-50-2Relevant academic research and scientific papers
A Novel Cyclization of 1,2-Bis(2,2-dibromocyclopropyl)benzenes with Methyllithium
Hoehn, Juergen,Weyerstahl, Peter
, p. 808 - 814 (2007/10/02)
The CBr2 bis adducts 7, 8, and 10 react with MeLi at - 78 deg C to give the dicyclopropanaphthalenes 17 - 19.Thus, from meso-7 syn-17, and from d,l-7 anti-17 are formed stereoselectively.The reaction may proceed via the intermediates A or B.The carbenoid
