851592-64-8Relevant articles and documents
Highly stereoselective epoxidation of a 4-methyl-5- (triethylsilyl)oxyallyl alcohol system with m-chloroperoxybenzoic acid
Maruyama, Kimiyuki,Ueda, Masato,Sasaki, Shinobu,Iwata, Yasuhiro,Miyazawa, Masahiro,Miyashita, Masaaki
, p. 4517 - 4520 (1998)
Epoxidation of 4-methyl-5-(triethylsilyl)oxyallyl alcohol system with m- chloroperoxybenzoic acid (MCPBA) has been found to occur highly stereoselectively and in high yields from the opposite side of the C5 triethylsilyloxy group regardless of
Tetramic acid antibiotics: Stereoselective synthesis of streptolic acid and tirandalydigin
Iwata, Yasuhiro,Maekawara, Naomi,Tanino, Keiji,Miyashita, Masaaki
, p. 1532 - 1536 (2007/10/03)
A new and promising methodology for the synthesis of the tetramic acid family of antibiotics was developed. The first synthesis of N-2,4- dimethoxybenzyl tirandalydigin (1), as well as a synthesis of streptolic acid (2), was achieved in a highly stereosel