851636-93-6

Basic information

• Product Name: 2-(3'-azidopropyl)-2-(pyrrolidinecarbon-1'-yl)cyclohex-3-enone
• Synonyms: 2-(3'-azidopropyl)-2-(pyrrolidinecarbon-1'-yl)cyclohex-3-enone
• CAS NO: 851636-93-6
• Molecular Weight: 276.338
• Mol File: 851636-93-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2-(3'-azidopropyl)-2-(pyrrolidinecarbon-1'-yl)cyclohex-3-enone(CAS DataBase Reference)
• NIST Chemistry Reference: 2-(3'-azidopropyl)-2-(pyrrolidinecarbon-1'-yl)cyclohex-3-enone(851636-93-6)
• EPA Substance Registry System: 2-(3'-azidopropyl)-2-(pyrrolidinecarbon-1'-yl)cyclohex-3-enone(851636-93-6)

Safety Data

• Hazardous Substances Data: 851636-93-6(Hazardous Substances Data)

Upstream product

• 58503-62-1 1-azido-3-iodopropane 
• 120173-04-8 (2-methoxyphenyl)(pyrrolidin-1-yl)methanone 

Relevant articles and documents

Facile C-N cleavage in a series of bridged lactams

A series of strained bi- and tricyclic amides has been shown to be unusually sensitive to cleavage of the C-N bond adjacent to the amide moiety. This bond undergoes facile breaking when subjected to treatment with H2/Pd(OH)2, MeI, and DDQ. In each case, the reaction is highly regioselective and mainly results in breaking the C-N bond that deviates the farthest from its natural planar state. Preliminary experiments that bear on the mechanisms of these reactions are described. Copyright