851877-06-0

Basic information

• Product Name: (2E,4E)-5-benzoyloxy-penta-2,4-dien-1-yl hydrogen maleate
• Synonyms: (2E,4E)-5-benzoyloxy-penta-2,4-dien-1-yl hydrogen maleate
• CAS NO: 851877-06-0
• Molecular Weight: 302.284
• Mol File: 851877-06-0.mol

Chemical Properties

• CAS DataBase Reference: (2E,4E)-5-benzoyloxy-penta-2,4-dien-1-yl hydrogen maleate(CAS DataBase Reference)
• NIST Chemistry Reference: (2E,4E)-5-benzoyloxy-penta-2,4-dien-1-yl hydrogen maleate(851877-06-0)
• EPA Substance Registry System: (2E,4E)-5-benzoyloxy-penta-2,4-dien-1-yl hydrogen maleate(851877-06-0)

Safety Data

• Hazardous Substances Data: 851877-06-0(Hazardous Substances Data)

Upstream product

• 108-31-6 maleic anhydride 
• 40418-53-9 1-(benzoyloxy)-5-hydroxy-1(E),3(E)-pentadiene 

Downstream Products

• 97308-29-7 (3aα,4β,5β,7aα)-5-(benzoyloxy)-1,3,3a,4,5,7a-hexahydro-3-oxo-4-isobenzofurancarboxylic acid 
• 114132-98-8 (3aα,4β,5β,7aα)-5-(benzoyloxy)-1,3,3a,4,5,7a-hexahydro-3-oxo-4-isobenzofurancarboxylic acid methyl ester 
• 851955-81-2 methyl (2E,4E)-5-benzoyloxypenta-2,4-dien-1-yl maleate 

Relevant articles and documents

On the Diels-Alder reactions of pentadienyl maleates and citraconates

Reactions between conjugated dienols and maleic anhydride provide either cis-fused or trans-fused bicyclic products as major products, depending upon how the reaction is carried out. Simply mixing the two reactants together generally leads to cis-fused la

Intramolecular Diels-Alder reactions of ester-linked 1,3,8-nonatrienes

Penta-1,3-dienyl acrylates undergo kinetically controlled intramolecular Diels-Alder (IMDA) reactions and DFT calculations (B3LYP/6-31+G(d)) predict stereoselectivities that are in very good agreement with the experimental values. The nature of the diene