851877-06-0Relevant articles and documents
On the Diels-Alder reactions of pentadienyl maleates and citraconates
Cayzer, Tory N.,Lilly, Michael J.,Williamson, Rachel M.,Paddon-Row, Michael N.,Sherburn, Michael S.
, p. 1302 - 1307 (2005)
Reactions between conjugated dienols and maleic anhydride provide either cis-fused or trans-fused bicyclic products as major products, depending upon how the reaction is carried out. Simply mixing the two reactants together generally leads to cis-fused la
Intramolecular Diels-Alder reactions of ester-linked 1,3,8-nonatrienes
Cayzer, Tory N.,Paddon-Row, Michael N.,Moran, Damian,Payne, Alan D.,Sherburn, Michael S.,Turner, Peter
, p. 5561 - 5570 (2007/10/03)
Penta-1,3-dienyl acrylates undergo kinetically controlled intramolecular Diels-Alder (IMDA) reactions and DFT calculations (B3LYP/6-31+G(d)) predict stereoselectivities that are in very good agreement with the experimental values. The nature of the diene