851895-45-9

Upstream product

• 1350973-20-4 methyl 4-O-(R)-benzyl-α-d1-2,3-di-O-benzyl-6-O-tert-butyldiphenylsilyl-α-D-glucopyranoside 
• 61866-19-1 (S)-benzyl-α-d1-4-methylbenzenesulfonate 
• 116730-42-8 4,5-bis(benzyloxy)-2-(tert-butyldimethylsilanyloxy)-6-methoxytetrahydropyran-3-ol 
• 7177-79-9 methyl 2,3-O-dibenzyl-4,6-O-benzylidene-α-D-glucopyranoside 
• 1256770-22-5 methyl 2,3-di-O-benzyl-4,6-O-(1-(2)H-benzylidene)-α-D-glucopyranoside 

Relevant academic research and scientific papers

Deuterium-isotope study on the reductive ring opening of benzylidene acetals

Specific deuterated reference compounds were prepared to probe the stereoselectivity of the reductive ring opening of carbohydrate-based benzylidene-type acetals. AlD3 revealed a retentive stereoselectivity probably through the rare SN/su

Reductive openings of benzylidene acetals revisited: A mechanistic scheme for regio- and stereoselectivity

Despite the importance of regioselective reductive openings of cyclic acetals, mechanistic details are scarce. In this study 4,6-O-benzylidene acetals were used as model compounds for deciphering the mechanism of regioselective openings using a variety of