851973-84-7Relevant academic research and scientific papers
One-Pot Synthesis of Less Accessible N-Boc-Propargylic Amines through BF3-Catalyzed Alkynylation and Allylation Using Boronic Esters
Yasumoto, Kento,Kano, Taichi,Maruoka, Keiji
, (2019)
An efficient synthesis of α-alkynyl- or α-allyl-substituted N-Boc-propargylic amines is described via an alkynylation or allylation of alkynyl-substituted N-Boc-imines. Our strategy relies on the BF3-mediated in situ generation of alkynyl imine
Synthesis of multisubstituted 1,3-butadienes using the ruthenium-catalysed double addition of trimethylsilyldiazomethane to alkynylboronates
Morita, Ryotaro,Shirakawa, Eiji,Tsnchimoto, Teruhisa,Kawakami, Yusuke
, p. 1263 - 1268 (2007/10/03)
The ruthenium-catalysed double addition of trimethylsilyldiazomethane to alkynes developed by Dixneuf and co-workers was applied to the synthesis of 2-alkyl- or 2-aryl-3-(4,4,5,5-tetramethyl-l,3,2-dioxaborolan-2-yl)1,4- bis(trimethylsilyl)-1,3-butadienes
