852050-28-3

Basic information

• Product Name: 3-(p-fluorophenoxy)benzo[b]thiophene
• Synonyms: 3-(p-fluorophenoxy)benzo[b]thiophene
• CAS NO: 852050-28-3
• Molecular Weight: 244.289
• Mol File: 852050-28-3.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 3-(p-fluorophenoxy)benzo[b]thiophene(CAS DataBase Reference)
• NIST Chemistry Reference: 3-(p-fluorophenoxy)benzo[b]thiophene(852050-28-3)
• EPA Substance Registry System: 3-(p-fluorophenoxy)benzo[b]thiophene(852050-28-3)

Safety Data

• Hazardous Substances Data: 852050-28-3(Hazardous Substances Data)

Upstream product

• 95-15-8 Benzo[b]thiophene 
• 7342-82-7 3-Bromothianaphthene 
• 371-41-5 4-Fluorophenol 
• 57147-26-9 3-bromobenzothiophene S-oxide 
• 852050-20-5 3-(p-fluorophenoxy)benzo[b]thiophene 1-oxide 

Relevant articles and documents

Cu/Fe/O=PPh3-catalyzed etherification for the synthesis of aryl 3-benzo[b]thienyl ethers

Cu/Fe-cocatalyzed cross-coupling reactions between 3-bromobenzo[b]thiophene and hydroxyaryls are described herein. The combination of Cu and Fe catalysts is important for the progress of the reactions, and the use of triphenylphosphine oxide as a ligand suppresses the dehalogenation of 3-bromobenzo[b]thiophene, and promptly facilitates the reaction. The obtained aryl benzo[b]thienyl ethers can be converted to π-extended thienobenzofuran derivatives via Pd-catalyzed dehy-drogenative cyclizations.