852068-20-3

Upstream product

• 18162-48-6 tert-butyldimethylsilyl chloride 
• 852068-34-9 (2R,3S)-3-O-(t-butyldimethylsilyl)-1-O-(t-butyldiphenylsilyl)-2-{[(t-butyloxy)carbonyl]amino}-4-pentene-1,3-diol 
• 852068-33-8 (2R,3S)-1-O-(t-butyldiphenylsilyl)-2-{[(t-butyloxy)carbonyl]amino}-4-pentene-1,3-diol 

Downstream Products

• 1002114-65-9 N-[(1R,2S)-2-t-butyldimethylsiloxy-1-t-butyldiphenylsiloxymethyl-3-butenyl]-N-methyl-(2S,3S)-2-benzyloxycarbonylamino-3-hydroxybutanamide 
• 852068-21-4 C₇₃H₁₀₁N₅O₁₇Si₂ 

Relevant academic research and scientific papers

Development of a highly β-selective ribosylation reaction without using neighboring group participation: Total synthesis of (+)-caprazol, a core structure of caprazamycins

(Chemical Equation Presented) Full details of the total synthesis of (+)-caprazol are described. The key elements of our approach include the early stage introduction of the aminoribose in a highly β-selective manner, using the steric hindrance in the tra

Total synthesis of caprazol, a core structure of the caprazamycin antituberculosis antibiotics

TB and anti-TB: Two key steps in the synthesis of caprazol (1), a core structure of the antituberculosis antibiotics, are the introduction of an aminoribose moiety by β-selective ribosylation without the use of neighboring-group participation and the construction of the diazepanone moiety. (Chemical Equation Presented)