852203-52-2

Upstream product

• 1344148-85-1 (R)-methyl 4-(tert-butyldimethylsilyloxy)-2-(tert-butyldiphenylsilyloxy)butanoate 
• 1344148-86-2 (R)-4-(tert-butyldimethylsilyloxy)-2-(tert-butyldiphenylsilyloxy)butan-1-ol 
• 1344148-87-3 (R)-4-(tert-butyldimethylsilyloxy)-2-(tert-butyldiphenylsilyloxy)butanal 
• 1344148-89-5 C₂₅H₃₆O₄Si 
• 1344148-90-8 C₂₅H₃₄O₄Si 
• 1344148-91-9 C₃₅H₅₄O₃Si 
• 1344148-92-0 (R)-2-(tert-butyldiphenylsilyloxy)tetradecyl pivalate 
• 1344148-93-1 (R)-2-(tert-butyldiphenylsilyloxy)tetradecan-1-ol 
• 1344148-94-2 (R)-2-(tert-butyldiphenylsilyloxy)tetradecanal 
• 1344148-95-3 (R)-5-(tert-butyldiphenylsilyloxy)-1,1-diethoxyheptadec-2-yn-4-ol 
• 1353388-71-2 C₃₇H₆₀O₄Si 
• 1344148-78-2 (R)-tert-butyl(1-(furan-2-yl)tridecyloxy)diphenylsilane 
• 1344148-96-4 (R)-5-((R)-1-(tert-butyldiphenylsilyloxy)tridecyl)furan-2(5H)-one 
• 1431388-76-9 (1′R,5R)-5-{1′-[(tert-butyldiphenylsilyl)oxy]-2′-(hydroxy)ethyl}-5H-furan-2-one 

Relevant academic research and scientific papers

Synthesis of (-)-muricatacin from tri- O -acetyl- d -glucal

The total synthesis of (-)-muricatacin is achieved using commercially available tri-O-acetyl-d-glucal as the starting material. The structure of the intermediate chiral butenolide is established unambiguously by X-ray crystallographic analysis, which consequently leads to correction of a previous structural misassignment. Georg Thieme Verlag Stuttgart. New York.

Total synthesis of (-)-muricatacin

A total synthesis of (-)-muricatacin has been achieved using a commercially available starting material and our furan approach to oxacyclic systems, the proven scope of which is thus broadened.

(R)-2,3-Cyclohexylideneglyceraldehyde, a novel template for facile and simple entry into chiral hydroxy γ-lactones: Synthesis of (-)-muricatacin

(R)-2,3-Cyclohexylideneglyceraldehyde 1 has been used in a simple and efficient synthesis of (-)-muricatacin 10. The required chiron, syn-alkanetriol 2a was prepared by the reduction of a ketone 3 derived from 1.