85231-97-6

Basic information

• Product Name: C₁₇H₂₆NO₆P
• Synonyms: C₁₇H₂₆NO₆P
• CAS NO: 85231-97-6
• Molecular Weight: 371.37
• Mol File: 85231-97-6.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: C₁₇H₂₆NO₆P(CAS DataBase Reference)
• NIST Chemistry Reference: C₁₇H₂₆NO₆P(85231-97-6)
• EPA Substance Registry System: C₁₇H₂₆NO₆P(85231-97-6)

Safety Data

• Hazardous Substances Data: 85231-97-6(Hazardous Substances Data)

Upstream product

• 85232-02-6 diethyl N-tert-butyloxycarbonylphosphoramidate 
• 582-24-1 1-phenyl-2-hydroxyethanone 
• 20039-33-2 diethoxyphosphoryl isocyanate 
• 85232-03-7 Diethyl N-sodio-N-(tert-butoxycarbonyl)phosphoramidate 
• 70-11-1 α-bromoacetophenone 

Downstream Products

• 5468-37-1 2-aminoacetophenone hydrochloride 

Relevant articles and documents

New protocol for converting alcohols into amines

The reactions between diethyl N-(t-butoxycarbonyl)phosphoramidate 1, diisopropyl azodicarboxylate (DIAD), triphenylphosphine (TPP) and primary or secondary alcohols lead to the corresponding diethyl N-alkyl-N-(t-butoxycarbonyl)phosphoramidates 2a-o. Deprotection of crude 2 by refluxing with p-toluenesulfonic acid monohydrate in ethanol affords ammonium tosylates 3a-o in moderate to good overall yields. The N-alkylation of 1 proceeds stereoselectively with complete inversion of the configuration of the alkyl group.

Diethyl N-(t-Butoxycarbonyl)-phosphoramidate: A New, Useful Substitute of Phthalimide in Gabriel-Type Syntheses of Primary Amines

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