852317-16-9Relevant academic research and scientific papers
Highly modular synthesis of C1-symmetric aminosulfoximines and their use as ligands in copper-catalyzed asymmetric Mukaiyama-Aldol reactions
Langner, Martin,Remy, Pauline,Bolm, Carsten
, p. 6254 - 6265 (2007/10/03)
The development of C1-symmetric aminosulfoximines, their highly modular synthesis, and their application in enantioselective copper-catalyzed Mukaiyama-type aldol reactions between pyruvates and enolsilanes is described. In this context, the in
C1-symmetric aminosulfoximines as ligands in copper-catalyzed carbonyl-ene reactions
Langner, Martin,Rémy, Pauline,Bolm, Carsten
, p. 781 - 784 (2007/10/03)
Highly modular C1-symmetric aminosulfoximines were prepared and applied as chiral ligands in copper-catalyzed enantioselective carbonyl-ene reactions. The optimized system catalyzed the conversion of pyruvates and 1,1-disubstituted olefins yiel
