852339-67-4Relevant academic research and scientific papers
Mechanism-Based Design of an Amide-Directed Ni-Catalyzed Arylboration of Cyclopentene Derivatives
Lambright, Alison L.,Liu, Yanyao,Joyner, Isaac A.,Logan, Kaitlyn M.,Brown, M. Kevin
, p. 612 - 616 (2021)
A method for amide-directed Ni-catalyzed diastereoselective arylboration of cyclopentenes is disclosed. The reaction allows for the synthesis of sterically congested cyclopentane scaffolds that contain an easily derivatized boronic ester and amide functional handles. The nature of the amide directing group and its influence on the reaction outcome are investigated and ultimately reflect a predictably selective reaction based on the solvent and base counterion.
HETEROCYCLIC SPIRO COMPOUND
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Page/Page column 39; 40, (2008/06/13)
The compound represented by formula (I) (wherein D and G are cyclic group which may have a substituent(s) or alkyl which may have a substituent(s), W and Y are a bond or a spacer of which main chain has an atom number of 1-4, ringA and ringB are heterocyc
