85236-86-8Relevant academic research and scientific papers
Effect of para substituants on the molecular and electronic structures of sterically congested triplet diphenylcarbenes
Hu, Yingmo,Hirai, Katsuyuki,Tomioka, Hideo
, p. 9280 - 9284 (2007/10/03)
A series of triplet di(2,6-dimethylphenyl)carbenes (32) bearing nine symmetrical para di-substituents with well-distributed electronic properties have been generated by the irradiation of the corresponding diazo precursors and studied using ele
Polymethylated and poly(tert)butylated diphenylcarbenes. Generation, reactions, kinetics, and deuterium isotope effects of sterically congested triplet carbenes
Tomioka, Hideo,Okada, Hidetsumu,Watanabe, Tetsuya,Banno, Kohji,Komatsu, Kazunori,Hirai, Katsuyuki
, p. 1582 - 1593 (2007/10/03)
Dimesitylcarbene (2a) was shown to decay by undergoing dimerization and to have a half-life of 160 ms, some 5 orders of magnitude longer-lived than diphenylcarbene. Didurylcarbene (2b) was twice as long-lived as 2a, while decamethyldiphenylcarbene (2c) de
