85246-10-2Relevant academic research and scientific papers
REACTIONS OF HAFNIUM TETRACHLORIDE WITH THIO-SCHIFF BASES DERIVED FROM S-METHYLDITHIOCARBAZATE
Verma, V.,Kher, S.,Kapoor, R. N.
, p. 371 - 376 (2007/10/02)
The reactions of hafnium tetrachloride with thio-Schiff bases (derived from the condensation of S-methyldithiocarbazate with aldehydes/ketones) in different molar ratios have been carried out in refluxing dichloromethane.The products of the type, HfCl3(TSB), HfCl2(TSB)2,and HfCl2(TSB'), - and 2- are the anions of mono- and dibasic thio-Schiff bases, respectively were obtained and characterized on the basis of elemental analysis, electrical conductance measurements and spectral (infrared and electronic) data.
