852468-43-0

Basic information

• Product Name: ethyl (4S,2Z)-4-[tert-butoxycarbonyl-(4-methoxybenzyl)amino]-2-methyl-5-phenylpent-2-enoate
• Synonyms: ethyl (4S,2Z)-4-[tert-butoxycarbonyl-(4-methoxybenzyl)amino]-2-methyl-5-phenylpent-2-enoate
• CAS NO: 852468-43-0
• Molecular Weight: 453.579
• Mol File: 852468-43-0.mol

Chemical Properties

• CAS DataBase Reference: ethyl (4S,2Z)-4-[tert-butoxycarbonyl-(4-methoxybenzyl)amino]-2-methyl-5-phenylpent-2-enoate(CAS DataBase Reference)
• NIST Chemistry Reference: ethyl (4S,2Z)-4-[tert-butoxycarbonyl-(4-methoxybenzyl)amino]-2-methyl-5-phenylpent-2-enoate(852468-43-0)
• EPA Substance Registry System: ethyl (4S,2Z)-4-[tert-butoxycarbonyl-(4-methoxybenzyl)amino]-2-methyl-5-phenylpent-2-enoate(852468-43-0)

Safety Data

• Hazardous Substances Data: 852468-43-0(Hazardous Substances Data)

Upstream product

• 169905-22-0 N-(tert-Butoxycarbonyl)-N-(4-methoxybenzyl)-L-phenylalaninol 
• 91373-74-9 (2S)-2--3-phenyl-1-propanol 
• 7524-50-7 methyl (2S)-2-amino-3-phenylpropanoate hydrochloride 
• 59490-36-7 (2S)-methyl 2--3-phenyl-1-propanoate 
• 169905-23-1 (S)-2-[N-tert-butoxycarbonyl-N-(4′-Methoxybenzyl)amino]-3-phenylpropionaldehyde 
• 1099-45-2 ethyl (triphenylphosphoranylidene)acetate 
• 3699-66-9 ethyl 2-diethoxyphosphorylpropionate 

Downstream Products

• 934980-38-8 tert-butyl (2S,3Z)-(4-methoxybenzyl)(4-formyl-1-phenylpent-3-en-2-yl)carbamate 
• 934980-37-7 tert-butyl (2S,3Z)-(4-methoxybenzyl)(5-hydroxy-4-methyl-1-phenylpent-3-en-2-yl)carbamate 

Relevant articles and documents

Dynamic kinetic resolution during iron carbonyl promoted [6+2] ene-type reactions

Intramolecular coupling of cyclohexadiene-Fe(CO)3 complexes with pendant alkenes, to form spirolactams, proceed with excellent stereocontrol, using chiral amide substrates that lead to dynamic kinetic resolution.

Dynamic diastereoselectivity during iron carbonyl mediated spirocyclization reactions

Dynamic diastereoselectivity during Fe(CO)3 promoted [6 + 2] ene spirocyclization of 35a and 35b, having a chiral center on the pendent side chain, was investigated and gave rise to products 28a and 28b instead of four possible isomers. From th