852534-33-9Relevant academic research and scientific papers
2-α-hydroxyalkyl- and 2,7-di(α-hydroxyalkyl)-1,8- bis(dimethylamino)naphthalenes: Stabilization of nonconventional in/out conformers of "proton sponges" via n...H-O intramolecular hydrogen bonding. A remarkable kind of tandem nitrogen inversion
Pozharskii, Alexander F.,Degtyarev, Alexander V.,Ryabtsova, Oksana V.,Ozeryanskii, Valery A.,Kletskii, Mikhail E.,Starikova, Zoya A.,Sobczyk, Lucjan,Filarowski, Alexander
, p. 3006 - 3019 (2007)
(Chemical Equation Presented) A regular set of 2-(α-hydroxymethyl)- and 2,7-di(α-hydroxymethyl)-1,8-bis(dimethylamino)naphthalenes has been prepared. Their X-ray, NMR, and IR studies have demonstrated that in tertiary mono-alcohols the orientation of free
2-α-hydroxybenzhydryl- and 2,7-di(α-hydroxybenzhydryl)-1,8- bis(dimethylamino)naphthalenes: The first examples of stabilization of in/out proton sponge conformers by intramolecular hydrogen bonding. The most flattened amino group ever participating in IHB
Pozharskii, Alexander F.,Ryabtsova, Oksana V.,Ozeryanskii, Valery A.,Degtyarev, Alexander V.,Starikova, Zoya A.,Sobczyk, Lucjan,Filarowski, Alexander
, p. 3973 - 3976 (2005)
2-(α-Hydroxybenzhydryl)- 6 and 2,7-di(α-hydroxybenzhydryl)-1,8- bis(dimethylamino)naphthalenes 8 have been shown to exist in crystals as in/out conformers stabilized by O-H?N intramolecular hydrogen bonding. In agreement with X-ray studies, the NMR data a
