852631-03-9Relevant academic research and scientific papers
Water-induced rearrangement of a platinacyclic carbene produces a platinacyclic carbaphosphazene with an intraannular Pt-C bond in a Pt-N-P-N-P-C ring
Fang, Min,Jones, Nathan D.,Ferguson, Michael J.,McDonald, Robert,Cavell, Ronald G.
, p. 2005 - 2008 (2005)
(Chemical Equation Presented) An unusual synthetic route to the first example of a six-membered M-N-P-N-P-C metallacycle (M = metal atom) is reported which involves a water-induced rearrangement of the methylated Pt-N-P-C-P-N carbene 1 to the unique Pt-N-P-N-P-C platinacyclocarbaphosphazene 2. In the presence of a Lewis acid (LA), 2 converts into its orthometalated isomer 3 quantitatively. (OTf=CF3SO3).
