852667-82-4Relevant academic research and scientific papers
Quantitative analysis, occurrence, and stability of (E)-1-(2,3,6- trimethylphenyl)buta-1,3-diene in wine
Cox, Agnieszka,Capone, Dimitra L.,Elsey, Gordon M.,Perkins, Michael V.,Sefton, Mark A.
, p. 3584 - 3591 (2007/10/03)
A stable isotope dilution assay has been developed for quantification of (E)-1 -(2,3,6-trimethylphenyl)-buta-1,3-diene (4) in wine using a [ 2H6]-analogue. Using this method, 4 was found in 96 out of 97 white wines, but in none of 12 red wines analyzed. 4 was found to be most prevalent in Semillon wines, followed by Chardonnay, with Riesling showing the least amount of 4 among these three varieties. 4, like 1,1,6- trimethyldihydronaphthalene (TDN, 3), appears to be formed during the aging process. 4 was found to be unstable in model wine, and in both white and red wine, with the order of stability being model > white > red. In a PVPP-stripped red wine, the rate of degradation of 4 was substantially lessened, with the final concentrations very close to those observed in model wine. When treated with either grape or wine tannin extracts in model wine, the concentration of 4 was found to decrease to levels very close to those observed with an untreated red wine. When white wine was heated at 45°C, 4 was formed, indicating the presence of precursor forms. The amounts formed were much higher than those found in a commercial white wine. 4 was also observed in red wine heated to 45°C, but the concentration produced was much less than that with white wine.
