852695-06-8

Upstream product

• 652138-58-4 2-(2-cyanoethenyl)-N,N,N',N'-tetramethyl-1,4-benzenediamine 
• 153969-81-4 2-iodo-N,N,N',N'-tetramethyl-1,4-phenylenediamine 
• 652138-59-5 2-(2-cyanoethyl)-N,N,N',N'-tetramethyl-1,4-benzenediamine 

Downstream Products

• 1403967-56-5 N-(3-[2,5-bis(dimethylamino)phenyl]propyl)-N′-(2,5,8,12,15,18-hexaoxanonadec-10-yl)perylene-4,5,9,10-bis-(dicarboximide) 
• 1403967-57-6 N-(3-[2,5-bis(dimethylamino)phenyl]propyl)-N′-(2,5,15,18-tetraoxanonadec-10-yl)perylene-4,5,9,10-bis(dicarboximide) 

Relevant academic research and scientific papers

Donor-σ-Acceptor Molecules Incorporating a Nonadecyl-Swallowtailed Perylenediimide Acceptor

Donor-σ-acceptor-lipid molecules were prepared by using perylenetetracarboxylic diimide as the acceptor, starting from perylenetetracarboxylic dianhydride. One imide nitrogen was attached to a "swallowtail" lipid (a long alkyl tail connected at midchain), which imparts enough solubility to make the system tractable and provides a lipophilic region suitable for promoting Langmuir-Blodgett monolayer formation. The other imide link was to a donor group (pyrene, ferrocene, tetramethylphenylenediamine, phenyl) through a short alkyl σ bridge. Features of the 1H and 13C NMR spectra of swallowtailed perylenediimides are interpreted as resulting from restricted rotation about the imide C-N bond; the 13C NMR spectra and stereochemistry of these molecules are contrasted with the case of the related bis-(2,5-di-tert-butylphenyl)perylenetetracarboxylic diimide.