852719-97-2Relevant academic research and scientific papers
Syntheses and structures of homo- and heterobimetallic complexes containing a (cyclopentadienone)rhodium(I) fragment
Gauthier, Sebastien,Scopelliti, Rosario,Severin, Kay
, p. 435 - 446 (2005)
The reaction of [RhCl(n4-Ph2R2C 4CO)]2 (R = Ph, 2-naphthyl) with the dimeric complexes [RuCl2(p-cymene)]2 p-cymene = 1-methyl-4-(1-methylethyl) benzene, [RuCl2(1,3,5-Et3C6H3)] 2, [MCl2(Cp*)]2 (M = Rh, Ir; Cp* = 1,2,3,4,5-pentamethylcyclopenta-2,4-dien-1-yl), [RuCl2(CO) 3]2, [RuCl2(dcypb)(CO)]2 (dcypb = butane-l,4-diylbis[dicyclohexylphosphine]), [(dppb)ClRu(μ-Cl) 2(μ-OH2)RuCl(dppb)] (dppb = butane-1,4- diylbis[diphenylphosphine]), and [(dcypb)(N2)Ru(μ-Cl) 3RuCl(dcypb)] was investigated. In all cases, mixed, chloro-bridged complexes were formed in quantitative yield (see 5-8, 9-16, 18, 19, 21, and 22). The six new complexes 5, 8, 9,13, 15, and 22 were characterized by single-crystal X-ray analysis (Figs. 1-3).
