85280-22-4

Basic information

• Product Name: (1R,2S)-1-aminomethyl-2-methylcyclohexylamine
• CAS NO: 85280-22-4
• Molecular Weight: 142.244
• Mol File: 85280-22-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (1R,2S)-1-aminomethyl-2-methylcyclohexylamine(CAS DataBase Reference)
• NIST Chemistry Reference: (1R,2S)-1-aminomethyl-2-methylcyclohexylamine(85280-22-4)
• EPA Substance Registry System: (1R,2S)-1-aminomethyl-2-methylcyclohexylamine(85280-22-4)

Safety Data

• Hazardous Substances Data: 85280-22-4(Hazardous Substances Data)

Upstream product

• 583-60-8 2-Methylcyclohexanone 
• 64384-44-7 1-amino-2-methylcyclohexanecarbonitrile 

Relevant articles and documents

Studies of the Metal Complexes of Cyclohexane Derivatives. VII. Preparation and Properties of Platinum(II) and Cobalt(III) Complexes of (1R,2S)-1-Aminomethyl-2-methylcyclohexylamine

Optically active (1R,2S)-l-aminomethyl-2-methylcyclohexylamine (R,S-2m-amcha) was synthesized and two Pt(II) and two types of Co(III) complexes containing this ligand were prepared. 1H-NMR and 13C-NMR spectra of the Pt(II) complexes and CD spectrum of trans-+ indicated that the chelate ring takes predominantly the λ conformation with the equatorial C1-C2 bond of the cyclohexane ring.The absolute configuration of the ligand has been assigned on the basis of the conformation of the complexes.All possible isomers of the tris Co(III) complex, fac-Δ(lel3), mer-Δ(lel3), mer-Λ(ob3), and fac-Λ(ob3), were isolated and characterized.