852925-22-5

Basic information

• Product Name: (1R,2Z)-1-(4R,5R)-5-[(benzyloxy)methyl]-2,2-dimethyl-1,3-dioxolan-4-yl-5-[(1,1,1-triisopropylsilyl)oxy]-2-penten-1-ol
• Synonyms: (1R,2Z)-1-(4R,5R)-5-[(benzyloxy)methyl]-2,2-dimethyl-1,3-dioxolan-4-yl-5-[(1,1,1-triisopropylsilyl)oxy]-2-penten-1-ol
• CAS NO: 852925-22-5
• Molecular Weight: 478.745
• Mol File: 852925-22-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (1R,2Z)-1-(4R,5R)-5-[(benzyloxy)methyl]-2,2-dimethyl-1,3-dioxolan-4-yl-5-[(1,1,1-triisopropylsilyl)oxy]-2-penten-1-ol(CAS DataBase Reference)
• NIST Chemistry Reference: (1R,2Z)-1-(4R,5R)-5-[(benzyloxy)methyl]-2,2-dimethyl-1,3-dioxolan-4-yl-5-[(1,1,1-triisopropylsilyl)oxy]-2-penten-1-ol(852925-22-5)
• EPA Substance Registry System: (1R,2Z)-1-(4R,5R)-5-[(benzyloxy)methyl]-2,2-dimethyl-1,3-dioxolan-4-yl-5-[(1,1,1-triisopropylsilyl)oxy]-2-penten-1-ol(852925-22-5)

Safety Data

• Hazardous Substances Data: 852925-22-5(Hazardous Substances Data)

Upstream product

• 153495-48-8 but-3-ynyloxy-triisopropyl-silane 
• 81801-09-4 4-O-benzyl-2,3-O-isopropylidene-D-threose 
• 13154-24-0 triisopropylsilyl chloride 

Downstream Products

• 852925-23-6 (1R,2Z)-1-(4R,5R)-5-[(benzyloxy)methyl]-2,2-dimethyl-1,3-dioxolan-4-yl-2-pentene-1,5-diol 
• 852925-27-0 (2R,4R,5R,6R)-6-((4R,5R)-5-[(benzyloxy)methyl]-2,2-dimethyl-1,3-dioxolan-4-yl)-4,5-dihydroxytetrahydro-2H-2-pyranyl acetate 
• 852925-25-8 (2R,6R)-6-((4R,5R)-5-[(benzyloxy)methyl]-2,2-dimethyl-1,3-dioxolan-4-yl)-3,6-dihydro-2H-2-pyranyl acetate 

Relevant articles and documents

A C-glycosidation approach to the central core of amphidinol 3: Synthesis of the C39-C52 fragment

(Chemical Equation Presented) A concise route to an advance precursor (3) of the central core of amphidinol 3, a natural occurring polyketide, has been developed by applying a reductive lithiation as key step. The origin of the diastereoselectivity of thi