85296-26-0Relevant academic research and scientific papers
STEREOCHEMISTRY OF THE THIYLATION OF 1,2-DINITROALKENES AND 1,4-DINITRO-1,3-DIENES
Mukhina, E. S.,Berkova, G. A.,Pavlova, Z. F.,Lipina, E. S.,Perekalin, V. V.
, p. 1249 - 1254 (2007/10/02)
In thiylation with arenethiolates 1,2-dinitroalkenes form 1-nitro-2-arylthioalkenes in the more stable Z form, and in the absence of a base they form a mixture of the Z and E isomers.During thiylation with arenethiols 1,4-dinitro-1,3-butadienes only give (E,E)-1-nitro-4-arylthio-1,3-dienes.
Nucleophile and Nucleofuge Effects, Catalysis, and Stereochemistry in Vinylic Substitution of Electrophilic Nitro Olefins
Rappoport, Zvi,Topol, Alain
, p. 5967 - 5977 (2007/10/02)
The substitution of (E)- and (Z)-β-iodo-α-nitrostilbenes (E-3-I and Z-3-I) and of the (E)-β-chloro (E-3-Cl) and of (E)-β-nitro (E-3-NO2) analogues with several nucleophiles were studied in MeCN and EtOH.Amine catalysis in the substitution with morpholine
Conjugated dinitroalkenes in reaction with alkyl and aryl hydrosulfides
Pavlova, Z. F.,Kasem, Ya. A.,Lipina, E. S.,Perekalin, V. V.
, p. 2227 - 2229 (2007/10/02)
Highly electrophilic conjugated 1,2-dinitroalkenes react actively with alkyl and aryl hydrosulfides (ethyl hydrosulfide, thiophenol, p-chlorothiophenol) in the presence of bases to form products from substitution of the nitro group, i.e., nitro(alkyl)aryl
