853-95-2

Upstream product

• 529-34-0 3,4-dihydronaphthalene-1(2H)-one 
• 119-26-6 (2,4-dinitro-phenyl)-hydrazine 
• 62952-26-5 1-oxo-1,2,3,4-tetrahydronaphthalene-2-carboxylic acid 
• 529-33-9 1,2,3,4-Tetrahydro-1-naphthol 

Downstream Products

• 73686-17-6 2-{1-[(2,4-Dinitro-phenyl)-hydrazono]-1,2,3,4-tetrahydro-naphthalen-2-yl}-malonic acid diethyl ester 
• 529-34-0 3,4-dihydronaphthalene-1(2H)-one 
• 51758-77-1 N-(2,4-Dinitro-phenyl)-N'-[2-(2-methoxy-ethoxy)-3,4-dihydro-2H-naphthalen-(1Z)-ylidene]-hydrazine 
• 51758-78-2 2-hydroxy-3,4-dihydro-2H-naphthalen-1-one-(2,4-dinitro-phenylhydrazone) 

Relevant academic research and scientific papers

Fe (III) complexes of a bis-benzimidazolyl diamide ligand: Spectral and Catalytic studies

A new tetradentate bis benzimidaozlyl diamide ligand N,N′-Bis (benzimidazol-2-yl-methyl)-hexane-1,6-dicarboxamide (GBSA) has been synthesized and utilized to prepare new Fe(III) complexes with exogenous anionic ligand X = Cl- and NO3-. Isomer shift values are in the range found for Iron in the +3 oxidation state while Quadrupole Splitting indicates large distortion from a six coordinate geometry, a finding supported by low temperature EPR work. The E1/2 values are found to be quite cathodic indicating stability of the Iron (III) complexes. The oxidation of alcohols was investigated using [Fe(GBSA)Cl3] as the catalyst with TBHP as an alternate source of oxygen. The respective carbonyl products have been isolated and characterized by 1H NMR, electronic spectroscopy, mass and IR spectral studies.