85316-75-2

Basic information

• Product Name: 4-(1,1-Dimethyl-prop-2-ynyloxy)-3-methoxy-benzoic acid methyl ester
• Synonyms: 4-(1,1-Dimethyl-prop-2-ynyloxy)-3-methoxy-benzoic acid methyl ester
• CAS NO: 85316-75-2
• Molecular Weight: 248.279
• Mol File: 85316-75-2.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 4-(1,1-Dimethyl-prop-2-ynyloxy)-3-methoxy-benzoic acid methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: 4-(1,1-Dimethyl-prop-2-ynyloxy)-3-methoxy-benzoic acid methyl ester(85316-75-2)
• EPA Substance Registry System: 4-(1,1-Dimethyl-prop-2-ynyloxy)-3-methoxy-benzoic acid methyl ester(85316-75-2)

Safety Data

• Hazardous Substances Data: 85316-75-2(Hazardous Substances Data)

Upstream product

• 1111-97-3 3-chloro-3-methylbut-1-yne 
• 3943-74-6 4-hydroxy-3-methoxybenzoic acid methyl ester 

Downstream Products

• 85316-77-4 methyl 4-hydroxy-3-methoxy-5-(3-methylbut-2-enyl)benzoate 

Relevant articles and documents

Cesium fluoride-mediated claisen rearrangements of phenyl propargyl ethers: Substituent effects of an orthoalkoxy group on the benzene ring or modified propargyl residues

The expected 7-alkoxy-2-methylbenzo[b]furans were effectively given in the CsF-mediated Claisen rearrangement of phenyl propargyl ethers with an o-alkoxy substituent on the benzene ring. On the other hand CsF did not affect the production of the corresponding benzo[b]furans when ethers, carrying a propargyl residue modified by either 1,1-dimethyl or 3-ethoxycarbonyl functions, were used as substrates in the rearrangement.