853200-80-3Relevant academic research and scientific papers
Preparation and characterization of carboximidate iron(II) complexes
Chen, Liyi,Zhang, Wen,Huang, Shuping,Jin, Xianglin,Sun, Wen-Hua
, p. 41 - 43 (2005)
The reactions of C5H4NCH=NNHC(=O)Ph with Fe(II) chloride gave dinuclear [Fe2(C5H4NC(OEt)=NNHC(= O)Ph)2(μ-OR)2Cl2]) in alcohol and mononuclear complex [C5H4NCH=NNHC(=O)Ph]FeCl2 in THF, in which the ferrous ion assisted the transformation of CHN group into carboximide ester of the ligand. The reactions of C5H 4NCH=NNHC(=O)Ph (1) with Fe(II) chloride gave [Fe2(C 5H4NC(OEt)=NNHC(=O)Ph)2(μ-OEt) 2Cl2]) (2) in ethanol and [Fe2(C 5H4NC(OMe)=NNHC(=O)Ph)2(μ-OMe) 2Cl2] (3) in methanol as well as [Fe(C5H 4NCH=NNHC(=O)Ph)Cl2] (4) in tetrahydrofuran, respectively. The X-ray diffraction analysis reveals their structures and complex 4 is proposed as an intermediate of formation of complexes 2 and 3.
