85332-06-5Relevant academic research and scientific papers
SOME PECULIAR CASES OF 7-TELESUBSTITUTION BY ANIONIC PHOSPHORUS NUCLEOPHILES ON 2-HALOTROPONES
Cavazza, Marino,Morganti, Gioia,Veracini, Carlo A.
, p. 4115 - 4118 (1982)
Both 2-chloro- and 2-fluorotropone were found to react with lithium diphenylphosphide in teterahydrofuran to give 2-diphenylphosphino tropone in what constitutes the first example of telesubstitution by an anionic nucleophile in a non-protic solvent on tropones carrying nucleofugal groups; lithium diphenylphosphide oxide showed the same behaviour.
