85339-36-2

Upstream product

• 146174-59-6 5-benzyloxymethyl-2-oxo-4-(4-tolylsulfonyl)tetrahydrofuran 
• 2930-05-4 Benzyloxymethyl-oxiran 
• 79-22-1 methyl chloroformate 
• 74-88-4 methyl iodide 
• 146174-51-8 5-benzyloxymethyl-2-hydroxy-4-(4-tolylsulfonyl)tetrahydrofuran 
• 14593-43-2 benzyl allyl ether 
• 60656-87-3 benzyloxyacetoaldehyde 
• 185811-92-1 (Z)-1,5-bis(benzyloxy)-3-(4-tolylsulfonyl)-4-penten-2-ol 
• 1228459-20-8 C₁₄H₁₆O₃ 

Downstream Products

• 113801-71-1 (4R,5S)-5-Benzyloxymethyl-4-(1-cyclohexylmethyl-vinyl)-dihydro-furan-2-one 
• 113801-70-0 2-((2S,3S)-2-Benzyloxymethyl-4-isobutyryl-5-oxo-tetrahydro-furan-3-yl)-2-(1-ethoxy-ethoxy)-4-methyl-pentanenitrile 
• 1361200-06-7 5-(benzyloxymethyl)furan-2-yl diphenyl phosphate 
• 1361200-12-5 dimethyl 1-(benzyloxymethyl)-4-(diphenoxyphosphoryloxy)-7-oxabicyclo[2.2.1]hepta-2,5-diene-2,3-dicarboxylate 
• 113801-75-5 (3S,4R,5S)-5-Benzyloxymethyl-4-((S)-2-cyclohexyl-1-methoxymethoxy-ethyl)-3-isobutyryl-3-methyl-dihydro-furan-2-one 
• 113801-75-5 (3S,4R,5S)-5-Benzyloxymethyl-4-((R)-2-cyclohexyl-1-methoxymethoxy-ethyl)-3-isobutyryl-3-methyl-dihydro-furan-2-one 
• 113801-74-4 (4R,5S)-5-Benzyloxymethyl-4-((S)-2-cyclohexyl-1-methoxymethoxy-ethyl)-dihydro-furan-2-one 
• 113801-74-4 (4R,5S)-5-Benzyloxymethyl-4-((R)-2-cyclohexyl-1-methoxymethoxy-ethyl)-dihydro-furan-2-one 
• 113801-73-3 (4R,5S)-5-Benzyloxymethyl-4-((S)-2-cyclohexyl-1-hydroxy-ethyl)-dihydro-furan-2-one 
• 113801-73-3 (4R,5S)-5-Benzyloxymethyl-4-((R)-2-cyclohexyl-1-hydroxy-ethyl)-dihydro-furan-2-one 
• 113801-68-6 (3S,4S,5S)-5-Benzyloxymethyl-4-(2-cyclohexyl-acetyl)-3-isobutyryl-3-methyl-dihydro-furan-2-one 
• 113801-72-2 (3S,4S,5S)-5-Benzyloxymethyl-4-(1-cyclohexylmethyl-vinyl)-3-isobutyryl-3-methyl-dihydro-furan-2-one 
• 113801-66-4 (3S,3aR,4S,6R,6aS)-3-Benzyloxymethyl-4-cyclohexylmethyl-6-hydroxy-6-isopropyl-6a-methyl-tetrahydro-furo[3,4-c]furan-1-one 
• 113801-80-2 (4R,5S)-5-Benzyloxymethyl-4-(1-cyclohexylmethyl-vinyl)-3-isobutyryl-dihydro-furan-2-one 

Relevant academic research and scientific papers

The catalytic performance of Ru-NHC alkylidene complexes: PCy3 versus pyridine as the dissociating ligand

The catalytic performance of NHC-ligated Ru-indenylidene or benzylidene complexes bearing a tricyclohexylphosphine or a pyridine ligand in ring closing metathesis (RCM), cross metathesis, and ring closing enyne metathesis (RCEYM) reactions is compared. While the PCy3 complexes perform significantly better in RCM and RCEYM reactions than the pyridine complex, all catalysts show similar activity in cross metathesis reactions.

A facile solid-phase synthesis of substituted 2(5H)-furanones with sulfone traceless linker

A novel solid-phase synthetic method for substituted 2(5H)-furanones with traceless sulfone linker strategy has been developed. The products were obtained in good yields and excellent purities.

(Alkoxyallyl)sulfones as enal β-anion equivalents. Synthesis of 5-substituted 2(5H)-furanones

2(5H)-Furanones 14 may be prepared in a four-step sequence starting from (alkoxyallyl)sulfone 10 and aldehydes.

1-Benzyloxy-3-(p-tolylsulfonyl)propene as an acrolein β-anion equivalent. Synthesis of 4-substituted 2-butenolides

Lithiation of 1-benzyloxy-3-(p-tolylsulfonyl)propene 6 and reaction with aldehydes give alcohols 7. Sequential hydrolysis-cyclization, oxidation and DBU-mediated elimination of dine elements of p-TolSO2H gives 4-substituted 2-butenolides 10 in good overall yield.