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• 67734-62-7 [(C₅H₅)(CO)2Mo(C₆H₅CN(CH₃)C(C₆H₅)N(CH₃))]⁽¹⁺⁾*PF₆^(1-)=[(C₅H₅)(CO)2Mo(C₆H₅CN(CH₃)C(C₆H₅)N(CH₃))]PF₆ 

Relevant academic research and scientific papers

UNTERSUCHUNGEN ZUR STRUKTUR UND STEREOCHEMIE DER ADDITIONSPRODUKTE VON NUKLEOPHILEN AN VON N-METHYLBENZIMIDCHLORID ABGELEITETE CARBENCHELATKOMPLEXE

In the reaction of (I) with C6H5MgBr the phenyl group adds to the carbene carbon atom giving the neutral complex (V).V crystallizes in the space group P21/c with the cell constants a 11.803(5), b 12.114(6), c 17.198(6) Angstroem, β 96.61(3)0, V 2431.2 Angstroem3, Z = 4, ρcalc 1.45 g cm-3.For 2979 reflections the R value is 5.1, Rw = 4.8.The stereoisomers IIIA and IIIB, formed in the H- addition to I, are 1H NMR spectroscopically investigated by means of Nuclear-Overhauser-Effect Difference Spectroscopy in order to elucidate the orientation of the incoming H substituent with respect to the C5H5 group.