85355-66-4Relevant academic research and scientific papers
BENZENESULFONYLCARBONITRILE OXIDE. 5. FACE SELECTIVITY OF CYCLOADDITION TO CHIRAL TERMINAL ALKENES
Wade, Peter A.,Singh, Shankar M.,Pillay, M. Krishna
, p. 601 - 612 (2007/10/02)
The diastereomer ratio for cycloaddition of benzenesulfonylcarbonitrile oxide (BSNO) to a series of (S)-vinylglycine-derived alkenes varied from 30:70 to 66:34 depending on the substituents at the chiral center.Isomer ratios were routinely determined by (
Benzenesulfonylcarbonitrile Oxide. 4. Substitution Reactions of 3-(Phenylsulfonyl)isoxazolines
Wade, P. A.,Yen, H.-K.,Hardinger, S. A.,Pillay, M. K.,Amin, N. V.,et al.
, p. 1796 - 1800 (2007/10/02)
3-(Phenylsulfonyl)isoxazolines, readily obtained from alkenes by cycloaddition with benzenesulfonylcarbonitrile oxide, undergo a variety of substitution reactions.Alkyl, aryl, and acetylenic lithium reagents, cyanide, lithium or sodium alkoxides, and sodi
