85356-46-3

Upstream product

• 85356-26-9 [3-Imino-2-methyl-1-phenyl-3-p-tolyl-prop-(Z)-ylidene]-p-tolyl-amine 

Relevant academic research and scientific papers

Reduction of 1,3-Diimines. A New and General Method of Synthesis of γ-Diamines, β-Amino Ketones, and Derivatives with Two and Three Chiral Centers

1,3-Diimes 1 are easily reduced with Na/i-PrOH to afford unsymmetrical N-substituted γ-diamines 8 in nearly quantitative yields.Since three chiral centers are generated, compounds 8 are isolated as a mixture of diastereoisomers which are easily separated.