85395-79-5Relevant academic research and scientific papers
OLIGOSACCHARIDES FROM "STANDARDIZED INTERMEDIATES". THE 2-AMINO-2-DEOXY-D-GALACTOSE ANALOG OF THE BLOOD-GROUP O(H) DETERMINANT, TYPE 2, AND ITS PRECURSORS
Nashed, Mina A.,Anderson, Laurens
, p. 53 - 62 (2007/10/02)
The selectively benzylated glycoside allyl 2-acetamido-4,6-di-O-benzyl-2-deoxy-β-D-galactopyranoside (4) was prepared from the corresponding derivative of 2-acetamido-2-deoxy-D-glucose via the p-bromobenzenesulfonate and the benzoate. 2-O-Benzoyl-3,4,6-tr
THE USE OF 2-O-ACYL-1-O-SULFONYL-D-GALACTOPYRANOSE DERIVATIVES IN β-D-GALACTOPYRANOSIDE SYNTHESIS
Vernay, Fredrick h.,Rachaman, Eliezer S.,Eby, Ronald,Schuerch, Conrad
, p. 267 - 274 (2007/10/02)
Several 1-O-sulfonyl derivatives of D-galactopyranose having a participating benzoyl or p-methoxybenzoyl group at O-2 were synthesized from the corresponding D-galactopyranosyl chloride derivatives by use of silver p-toluenesulfonate or trifluoroethanesulfonate in acetonitrile.The reaction of the 1-O-sulfonyl-D-galactopyranose derivatives with several alcohols in various solvents at different times and temperatures served as reactions to determine the best conditions for synthesizing stereoselectively β-D-galactopyranosides in high yields.This method was used to prepare, in good yield, several β-D-galactopyranosyl-containing disaccharides.
