854048-80-9Relevant academic research and scientific papers
Synthesis and activity of macrocyclized chiral Mn(III)-Schiff-base epoxidation catalysts
Martinez, Alexandre,Hemmert, Catherine,Gornitzka, Heinz,Meunier, Bernard
, p. 2163 - 2171 (2007/10/03)
A series of chiral macrocyclic Mn(III)Salen complexes has been prepared with two salicylidene moieties linked in their 3 and 3′ positions by aliphatic polyether bridges of variable lengths or by a more rigid aromatic junction arm. X-ray structures of ligand precursors and of complex 8 have been performed. All complexes have been used in the asymmetric epoxidation of 1,2-dihydronaphthalene with NaOCl as oxygen atom donor and exhibited modest enantiomeric excesses. Complex 10 was selected to be tested with two cis-disubstituted olefins and several oxidants, namely NaOCl, PhIO and n-Bu 4NHSO5. 2,2′-Dimethylchromene oxide was obtained from 2,2′-dimethylchromene with ee values of 56% and 74% when using 10 and NaOCl and PhIO, respectively.
