85407-70-1

Basic information

• Product Name: 4-tert-butyl-4'-iodo(bicyclo<2.1.1>hexane)
• CAS NO: 85407-70-1
• Molecular Weight: 344.279
• Mol File: 85407-70-1.mol

Chemical Properties

• CAS DataBase Reference: 4-tert-butyl-4'-iodo(bicyclo<2.1.1>hexane)(CAS DataBase Reference)
• NIST Chemistry Reference: 4-tert-butyl-4'-iodo(bicyclo<2.1.1>hexane)(85407-70-1)
• EPA Substance Registry System: 4-tert-butyl-4'-iodo(bicyclo<2.1.1>hexane)(85407-70-1)

Safety Data

• Hazardous Substances Data: 85407-70-1(Hazardous Substances Data)

Upstream product

• 594-19-4 tert.-butyl lithium 
• 85407-64-3 1,4-diiodobicyclo<2.1.1>hexane 

Relevant articles and documents

Propellane. Reaction of 1,4-Diiodobicyclohexane with tert-Butyllithium and with Potassium Atoms

The synthesis of 1,4-diiodobicyclohexane (5) is described.The reaction of 5 with tert-butyllithium in hexane gave the same type of products as previously observed in the reaction of 1,4-diiodonorbornane (2) with tert-butyllithium.Evidence has been presented indicating the latter reaction to proceed via propellane as an intermediate, and it appears likely that the propellane was involved in the former reaction.The reaction of 5 with potassium atoms in the gas phase led to the formation of an unstable compound which has been isolated in a nitrogen matrix and tentatively identified as the propellane on the basis of its infrared spectrum.