85417-35-2

Upstream product

• 644-97-3 Dichlorophenylphosphine 
• 151-10-0 1,3-Dimethoxybenzene 

Downstream Products

• 176207-46-8 (η(6)-hexamethylbenzene)Ru[PPh(2-O-C6H3-6-OMe)2] 
• 176207-47-9 Ru[PPh(2-O-C₆H₃-6-OMe)(C₆H₃-2,6-(MeO)2)]2(MeCN) 
• 256531-18-7 P(C₆H₅)(C₆H₃(OCH₃)2)2(CH₂Cl)⁽¹⁺⁾*RuCl₃(CH₃SOCH₃)3^(1-) = [P(C₆H₅)(C₆H₃(OCH₃)2)2(CH₂Cl)][RuCl₃(CH₃SOCH₃)3] 
• 256531-21-2 P(C₆H₅)(C₆H₃(OCH₃)2)2(CH₂Cl)⁽¹⁺⁾*RuCl(CH₃SOCH₃)2(P(C₆H₅)(C₆H₃O(OCH₃))2)^(1-) = [C₂₃H₂₅ClO₄P][C₂₄H₂₉ClO₆PRuS₂] 
• 330215-01-5 [(C₆H₄CH₂N(CH₃)2)PdCl(P(C₆H₅)(C₆H₃(OCH₃)2)2)] 
• 163960-18-7 (η(6)-p-cymene)RuCl[PPh(2-O-C6H3-6-OMe)(C6H3(OMe)2-2,6)] 
• 250592-36-0 [(η(5)-pentamethylcyclopentadienyl)IrCl(bis(2,6-dimethoxyphenyl)phenylphosphine-κP,OMe)][PF6] 
• 330215-04-8 [(C₆H₄CH₂N(CH₃)2)Pd(P(C₆H₅)(C₆H₃(OCH₃)2)2)]⁽¹⁺⁾*PF₆^(1-)=[(C₆H₄CH₂N(CH₃)2)Pd(P(C₆H₅)(C₆H₃(OCH₃)2)2)]PF₆ 
• 176301-03-4 (η(6)-1,2,3,4-tetramethylbenzene)RuCl[PPh(2-O-C6H3-6-OMe)(C6H3(OMe)2-2,6)] 
• 135765-16-1 C₂₃H₂₆O₄PS⁽¹⁺⁾*I^(1-) 
• 91608-22-9 Bis-(2,6-dimethoxy-phenyl)-phenyl-phosphane; compound with perchloric acid 
• 123317-14-6 Bis-(2,6-dimethoxy-phenyl)-phenyl-phosphane; hydrochloride 

Relevant academic research and scientific papers

A Highly Basic and Nucleophilic Triphenylphosphine, Tris(2,4,6-trimethoxyphenyl)phosphine, and Related Compounds

A series of methoxy substituted triphenylphosphines, R3-nPhnP , and their tertiary phosphonium perchlorates have been prepared.The basicity of the title compound, (1), in acetone was f

PHOSPHORORGANISCHE VERBINDUNGEN 101. TERTIAERE PHOSPHINE MIT ORTHOALKOXYPHENYL-GRUPPEN. Synthese und Eigenschaften

Alkylphenylethers, ortho-lithiated in good yields, are transformed according to scheme (1) to the triarylphosphines ArPPh2, Ar2PPh and Ar3P (Ar contains in all cases an ortho-alkoxy group) (Table 1.).Hydroquinonedialkylethers can be lithiated twice, forming the compounds 102 and 103.Table 2 summarizes some arylalkylethers (71 - 101) which were lithiated; table 7 presents 12 new arylalkylethers.The syntheses of triarylphosphines with one or two bulky groups (105 - 110) and of triarylphosphines with one or two 3,4-dialkoxyphenyl groups (111 - 114) are reported.The 31P-spectra of the compounds prepared are discussed with respect to the validity of the Tolman-rule.