85417-75-0Relevant academic research and scientific papers
DIBpillar[n]arenes (n = 5, 6): Syntheses, X-ray crystal structures, and complexation with n-octyltriethyl ammonium hexafluorophosphate
Han, Chengyou,Ma, Fengying,Zhang, Zibin,Xia, Binyuan,Yu, Yihua,Huang, Feihe
, p. 4360 - 4363 (2010)
Figure Presented. DIBPillar[n]arenes (n = 5, 6) were synthesized. They showed different host-guest properties with n-octyltriethyl ammonium hexafluorophosphate G due to their different cavity sizes. DIBpillar[5]arene showed no complexation with G, while D
Naphthalene diimide templated synthesis of pillar[6]arenes
Ke, Hua,Jiao, Chen,Qian, Yu-Heng,Lin, Mei-Jin,Chen, Jian-Zhong
, p. 339 - 342 (2015/03/30)
A facile method for the selective synthesis of pillar[6]arenes has been developed. Due to a strong electron donor-acceptor interaction between the electron-deficient naphthalene diimide and a precursor for the pillararene, 1,4-diisobutoxy-2,5-bis(methoxym
The Electrochemical Metoxylation of Dialkoxyaromatic Compounds and the Determination of Isomer Ratios by N.M.R. Spectroscopy
Elgy, Geraldine M.,Jennings, W. Brian,Pedler, Alan E.
, p. 1255 - 1260 (2007/10/02)
Electrolysis in methanol-KOH solution of p-diethoxy-, p-di-n-propoxy-, p-di-isopropoxy-, p-di-n-butoxy-, p-di-isobutoxy-, and p-di-s-butoxy-benzenes afforded the corresponding 3,6-dialkoxy-3,6-dimethoxy-cyclohexa-1,4-diene, shown by 1H n.m.r. spectroscopy to be an approximately equimolar mixture of cis- and trans-isomers.Likewise, from 9,10-diethoxyanthracene was obtained an equimolar mixture of the cis- and trans-isomers of 9,10-diethoxy-9,10-dimethoxy-9,10-dihydroanthracene.
PHOSPHORORGANISCHE VERBINDUNGEN 101. TERTIAERE PHOSPHINE MIT ORTHOALKOXYPHENYL-GRUPPEN. Synthese und Eigenschaften
Horner, L.,Simons, G.
, p. 189 - 210 (2007/10/02)
Alkylphenylethers, ortho-lithiated in good yields, are transformed according to scheme (1) to the triarylphosphines ArPPh2, Ar2PPh and Ar3P (Ar contains in all cases an ortho-alkoxy group) (Table 1.).Hydroquinonedialkylethers can be lithiated twice, forming the compounds 102 and 103.Table 2 summarizes some arylalkylethers (71 - 101) which were lithiated; table 7 presents 12 new arylalkylethers.The syntheses of triarylphosphines with one or two bulky groups (105 - 110) and of triarylphosphines with one or two 3,4-dialkoxyphenyl groups (111 - 114) are reported.The 31P-spectra of the compounds prepared are discussed with respect to the validity of the Tolman-rule.
