854252-01-0Relevant academic research and scientific papers
Bimetallic Complexes Supported by a Redox-Active Ligand with Fused Pincer-Type Coordination Sites
Wang, Denan,Lindeman, Sergey V.,Fiedler, Adam T.
, p. 8744 - 8754 (2015/09/21)
The remarkable chemistry of mononuclear complexes featuring tridentate, meridionally chelating "pincer" ligands has stimulated the development of ligand frameworks containing multiple pincer sites. Here, the coordination chemistry of a novel pentadentate
Tuning the electronic and steric parameters of a redox-active tris(amido) ligand
Munha, Rui F.,Zarkesh, Ryan A.,Heyduk, Alan F.
, p. 11244 - 11255 (2013/10/22)
A family of tantalum compounds was prepared to probe the electronic effects engendered by the addition of electron-donating or electron-withdrawing groups to the 4/4′ positions of the redox-active ligand derived from bis(2-isopropylamino-4-X-phenyl)amine
5(10H)-Phenazinyl Radicals and Corresponding 5,10-Dihydrophenazine Radical Cations: An EPR and ENDOR Study
Peraus, Gunfried,Neugebauer, Franz A.
, p. 715 - 746 (2007/10/02)
The 5(10H)-phenazinyl radicals 1b-k have been prepared by reduction of the corresponding phenazinium salts 6b-k with ascorbic acid or potassium hexacyanoferrate(II) and were studied using EPR, ENDOR and general triple resonance spectroscopy.The results led to a complete analysis and full assignment of the HFC constants.Our assignment differs from that previously proposed.In many details the spin delocalization in the 5(10H)-phenazinyl system corresponds to that in diphenyl aminyl.Protonation provided the corresponding radical cations 2b-k which were also studied.
