85428-27-9Relevant academic research and scientific papers
FORMATION AND REACTIONS OF TRICHLORO-γ-LACTONES
Takano, Seiichi,Nishizawa, Shin'ichi,Akiyama, Masashi,Ogasawara, Kunio
, p. 1779 - 1788 (2007/10/02)
The allyl trichloroacetates, (6) and (7), have been converted into the trichloro-γ-lactones, (8) and (9), by cuprous chloride.On dechlorination using tri-n-butyltin hydride, regioselective reaction has occurred initially at α position to convert the trich
L'ELDANOLIDE, PHEROMONE DES GLANDES ALAIRES DE LA PYRALE DE LA CANNE A SUCRE, ELDANA SACCHARINA (WLK.): STRUCTURE ET SYNTHESE DE SES DEUX ENANTIOMERES
Vigneron, J. P.,Meric, R.,Larcheveque, M.,Debal, A.,Lallemand, J. Y.,et al.
, p. 3521 - 3530 (2007/10/02)
The isolation and structure determination of eldanolide, the wing gland pheromone of the male African Sugar Cane Borer, Eldana saccharina (Wlk.) is described.The absolute configuration was determined as (3S, 4R) by comparison of the CD spectra of the natural pheromone with both synthetic enantiomers.
ABSOLUTE CONFIGURATION OF ELDANOLIDE, THE WING GLAND PHEROMONE OF THE MALE AFRICAN CANE BORER, ELDANA SACCHARINA (WLK.) SYNTHESES OF ITS (+) AND (-) ENANTIOMERS.
Vigneron, J. P.,Meric, R.,Larcheveque, M.,Debal, A.,Kunesch, G.,et al.
, p. 5051 - 5054 (2007/10/02)
Eldanolide 1, a novel terpenoid lactone pheromone, was shown to have (3S,4R) configuration by synthesis of both enantiomers and comparison of their CD with the natural pheromone.
