85434-22-6Relevant articles and documents
NOVEL "ONE-POT" PREPARATION OF TETRAHYDROBENZODIPYRAN-4-ONES. APPLICATION TO THE SYNTHESIS OF PRECOCENE ANALOGUES WITH CONDENSED DIHYDROPYRAN RINGS
Camps, F.,Colomina, O.,Coll, J.,Messeguer, A.
, p. 2955 - 2959 (1982)
A novel one-pot preparation of tetrahydrobenzodipyran-4-ones 5 and 6 involving the sequential condensation of resorcinols 7 with 3,3-dimethylacrylic acid (8) and 1,3-dichloro-3-methylbutane (10) in the presence of methanesulphonic acid (which acts as solvent and catalyst) and further conversion of tetrahydrobenzodipyran-4-ones to the corresponding dihydrobenzodipyrans 3 and 4, which are precocene analogues, is described.