854443-88-2

Upstream product

• 99-09-2 3-nitro-aniline 
• 854443-86-0 3-(2-methoxycarbonyl-2-methoxycarbonylamino-ethyl)-6-trifluoromethanesulfonyloxy-indole-1-carboxylic acid tert-butyl ester 
• 854443-87-1 3-(2-methoxycarbonyl-2-methoxycarbonylamino-ethyl)-6-(4,4,5,5-tetramethyl-[1,3,2]dioxaborolan-2-yl)-indole-1-carboxylic acid tert-butyl ester 
• 5459-50-7 2-iodo-5-nitroaniline 
• 943975-81-3 C₂₇H₃₇N₂O₈I 
• 943975-80-2 C₂₇H₃₉N₃O₈ 
• 943975-92-6 C₂₇H₃₇N₃O₁₀ 
• 943975-79-9 C₂₂H₂₉N₃O₈ 
• 943975-82-4 C₃₃H₄₉BN₂O₁₀ 
• 943975-93-7 2-amino-3-[6-(4,4,5,5-tetramethyl-[1,3,2]dioxaborolan-2-yl)-1H-indol-3-yl]-propionic acid methyl ester 
• 854443-93-9 2-[2-(3,5-dichloro-4-hydroxy-phenyl)-2-oxo-acetylamino]-3-[6-(4,4,5,5-tetramethyl-[1,3,2]dioxaborolan-2-yl)-1H-indol-3-yl]-propionic acid methyl ester 

Downstream Products

• 943975-91-5 C₄₈H₅₀N₄O₁₂BCl₄I 
• 1042907-28-7 C₆₈H₅₉BCl₆IN₇O₁₇ 
• 1042907-27-6 C₇₄H₇₃BCl₆IN₇O₁₇Si 
• 1225383-19-6 C₆H₂I(OSi(CH₃)2C(CH₃)3)2CHCOOCH₃(NHCOCHNHC₆H₂Cl₂(OSi(CH₃)2C(CH₃)3)COCHNH(COCOC₆H₂Cl₂OH)(CH₂C₈H₄NH)BO₂C₆H₁₂) 
• 854443-92-8 C₆₈H₅₉BCl₆IN₇O₁₇ 
• 854443-91-7 N-[{[tert-butylcarbamoyl-(4-hydroxy-3-iodo-phenyl)-methyl]-carbamoyl}-(3,5-dichloro-4-hydroxy-phenyl)-methyl]-2-[2-(3,5-dichloro-4-hydroxy-phenyl)-2-oxo-acetylamino]-3-[6-(4,4,5,5-tetramethyl-[1,3,2]dioxaborolan-2-yl)-1H-indol-3-yl]-propionamide 

Relevant academic research and scientific papers

Synthesis of DEFG ring of complestatin and chloropeptin I: Highly atropdiastereoselective macrocyclization by intramolecular Suzuki-Miyaura reaction

Palladium-catalyzed intramolecular Suzuki-Miyaura reaction of linear tripeptide (23) afforded the 16-membered DEFG ring of complestatin (3) in good yield with an excellent atropdiastereoselectivity. Acidic treatment of 3 triggers a stereospecific rearrang

Isocomplestatin: Total synthesis and stereochemical revision

A Pd-mediated method for preparation of the strained macrocyclic moiety of complestatins is disclosed. Through stereoselective synthesis of model macrocycles and the S atropisomer of complestatin, the stereochemical identity of the anti-HIV agent complest