854490-29-2

Upstream product

• 854490-42-9 (2R,4R,5R)-5-[3-(t-butyldimethylsilyloxy)propyl]-4-[(4-methoxybenzyloxy)methyl]-2-phenyl-1,3-dioxane 
• 854490-26-9 (2R,4R,5R)-4-hydroxymethyl-2-phenyl-5-(prop-2-enyl)-1,3-dioxane 
• 854490-27-0 (2R,4R,5R)-4-[(4-methoxybenzyloxy)methyl]-2-phenyl-5-(prop-2-enyl)-1,3-dioxane 
• 854490-28-1 (2R,4R,5R)-5-(3-hydroxypropyl)-4-[(4-methoxybenzyloxy)methyl]-2-phenyl-1,3-dioxane 
• 1125-88-8 benzaldehyde dimethyl acetal 

Downstream Products

• 854490-30-5 (2R,4R,5R)-5-[3-(t-butyldimethylsilyloxy)propyl]-4-formyl-2-phenyl-1,3-dioxane 

Relevant academic research and scientific papers

Total synthesis of (+)-tubelactomicin A. 1. Stereoselective synthesis of the lower-half segment by an intramolecular Diels-Alder approach

(Chemical Equation Presented) Starting from diethyl (R)-malate, synthesis of the lower-half segment of (+)-tubelactomicin A, a 16-membered macrolide antibiotic, has been achieved. The synthesis involved the highly endo- and π-facial selective intramolecul