85468-34-4Relevant academic research and scientific papers
Reaction of N-(2-Pyridylmethyl)-3,5-dimethylbenzamide and N-(3-Pyridylmethyl)-3,5-dimethylbenzamide N-Oxides with Acetic Anhydride
Brana, Miguel F.,Rodriguez, Maria Luz Lopez
, p. 1297 - 1300 (2007/10/02)
As a continuation of our work on the reaction of N-pyridylmethyl-3,5-dimethylbenzamide N-oxides with acetic anhydride, we now report a study of the reaction of N-(2-pyridylmethyl)-3,5-dimethylbenzamide N-oxide (5) and N-(3-pyridylmethyl)-3,5-dimethylbenzamide N-oxide (6) with acetic anhydride.Compound 5 gave N,N'-di(3,5-dimethylbenzoyl)-1,2-di(2-pyridyl)ethenediamine (7) and 3,5-dimethylbenzamide (8).Compound 6 afforded three products formulated as 2-acetoxy-3-(3,5-dimethylbenzoylaminomethyl)pyridine (12), 3-(3,5-dimethylbenzoylaminomethyl)-2-pyridone (13) and 5-(3,5-dimethylbenzoylaminomethyl)-2-pyridone (14).Analytical and spectral data are presented which support the structures proposed.
