854691-01-3

Upstream product

• 56613-80-0 D-2-phenylglycinol 
• 18162-48-6 tert-butyldimethylsilyl chloride 

Downstream Products

• 672343-20-3 2-(tert-butyl-dimethyl-silanyloxy)-(1R)-[2-(diphenyl-phosphinothioyl)-phenyl]-ethylamine 
• 672343-15-6 2-(tert-butyl-dimethyl-silanyloxy)-(1R)-(2-iodo-phenyl)-ethylamine 
• 672343-26-9 2-adamantan-1-yl-(4R)-[2-(diphenyl-phosphinothioyl)-phenyl]-4,5-dihydro-oxazole 
• 672343-24-7 2-(3,5-di-tert-butyl-phenyl)-(4R)-[2-(diphenyl-phosphinothioyl)-phenyl]-4,5-dihydro-oxazole 
• 672343-33-8 2-adamantan-1-yl-(4R)-(2-diphenyl-phosphanyl-phenyl)-4,5-dihydro-oxazole 
• 672343-27-0 2-tert-butyl-(4R)-[2-(dicyclohexyl-phosphinothioyl)-phenyl]-4,5-dihydro-oxazole 
• 672343-23-6 2-benzhydryl-(4R)-[2-(diphenyl-phosphinothioyl)-phenyl]-4,5-dihydro-oxazole 
• 672343-16-7 2-tert-butyl-(4R)-(2-iodo-phenyl)-4,5-dihydro-oxazole 
• 861890-07-5 2-tert-bytyl-(4R)-[2-(diphenyl-phosphinothioyl)-phenyl]-4,5-dihydro-oxazole 
• 861890-06-4 2-hydroxy-(1R)-[2-(diphenyl-phosphinothioyl)-phenyl]-ethylamine 
• 672343-22-5 2-(tert-butyl-dimethyl-silanyloxy)-(1R)-[2-(dicyclohexyl-phosphinothioyl)-phenyl]-ethylamine 

Relevant academic research and scientific papers

A new class of readily available and conformationally rigid phosphino-oxazoline ligands for asymmetric catalysis

A new class of conformationally rigid phosphino-oxazoline ligands 3 were synthesized via an efficient ortho-substitution of phenyl glycinol as the key step. Divergent synthetic routes for easy ligand modulation, as well as a procedure suitable for scale-u

New oxazoline ligands for asymmetric catalysis

A chiral ligand represented by the formula and its enantiomer: wherein A, X, Y and Z are as defined in the specification is provided. Also provided is a process of making the chiral ligands and catalysts prepared from these ligands and a transition metal,

Synthesis of a New Class of Conformationally Rigid Phosphino-oxazolines: Highly Enantioselective Ligands for Ir-Catalyzed Asymmetric Hydrogenation

(Equation presented) A new class of conformationally rigid phosphino-oxazoline ligands were synthesized from readily available enantiopure phenyl glycinol. Ir complexes with these ligands are air-stable and highly enantioselective catalysts for asymmetric