854714-00-4

Basic information

• Product Name: Cyclohexanol, 1-(3,5-dimethylphenyl)-
• CAS NO: 854714-00-4
• Molecular Formula: C14H20O
• Molecular Weight: 204.312
• Mol File: 854714-00-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Cyclohexanol, 1-(3,5-dimethylphenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Cyclohexanol, 1-(3,5-dimethylphenyl)-(854714-00-4)
• EPA Substance Registry System: Cyclohexanol, 1-(3,5-dimethylphenyl)-(854714-00-4)

Safety Data

• Hazardous Substances Data: 854714-00-4(Hazardous Substances Data)

Upstream product

• 34696-73-6 3,5-dimethyphenylmagnesium bromide 
• 108-94-1 cyclohexanone 
• 556-96-7 5-bromo-1,3-xylene 

Downstream Products

• 107517-89-5 1-cyclohex-1-en-1-yl-3,5-dimethylbenzene 
• 857481-29-9 6-(3,5-dimethylphenyl)-6-oxohexanoic acid 
• 62315-36-0 6-(3,5-dimethyl-phenyl)-hexanoic acid 
• 17057-88-4 3,5-dimethylbiphenyl 

Relevant articles and documents

Remaekable effect of subtle structural change of chiral pseudo-18-crown-6 on enantiomer-selectivity in complexation with chiral amino alcohols

Chiral receptors [(S,S)-1] and [(S,S,S,S)-2] having 1,2-dialkoxy-1-(3,5-dimethylphenyl)ethane and 1,2-dialkoxy-1-(3,5-dimethyl phenyl)cyclohexane as chiral building blocks, respectively, were prepared. Thermodynamic parameters of complexations of these and structurally related receptors [(S,S)-3] and [(S,S,S,S)-4] with 2-amino-l-propanol (5), 2-amino-2-phenylethanol (6), and 3-methylbutan-l-ol (7) in chloroform were determined. It was found that the host-guest systems that have same enantiomer-selectivity at 25°C showed opposite selectivity in the enthalpy term. For example, complexations of both (S,S)-1 and (S,S)-3 with 5 are R-selective at 25°C (ΔΔG = 2.2 and 3.8 kJ mol-1, respectively), whereas in terms of the enthalpy of complexation the former is S-selective (ΔΔH = 22 kJ mol-1) but the latter is R-selective (ΔΔH = 10 kJ mol-1).