855313-96-1Relevant academic research and scientific papers
Hydrosilylation and Hydrogermylation of CO2 and CS2 by Al and Ga Functionalized Silanes and Germanes – Cooperative Reactivity with Formation of Silyl Formates and Disilylacetals
Tolzmann, Michael,Schürmann, Lina,Hepp, Alexander,Uhl, Werner,Layh, Marcus
, p. 4024 - 4036 (2020)
Hydrometallation of the alkynylelement hydrides iPr2E(H)–C≡C-tBu (1; E = Si, Ge) with R2M–H [M = Al, Ga; R = tBu, CH(SiMe3)2] afforded in moderate yields the Al and Ga functionalized alkenylsilanes and -germanes
Sodium triethylborohydride as a catalyst for the dehydrogenative silylation of terminal alkynes with hydrosilanes
Skrodzki, Maciej,Witomska, Samanta,Pawlu?, Piotr
supporting information, p. 5948 - 5951 (2018/05/14)
The first example of sodium triethylborohydride-catalyzed C(sp)-H bond silylation is reported. The reaction of aromatic and aliphatic alkynes with aromatic hydrosilanes and hydrosiloxanes proceeded in a highly selective manner to afford dehydrocoupling pr
η1:η2-alkynyl-bridged W-Si complexes: Formation, structure, and reaction with acetone
Sakaba, Hiroyuki,Yoshida, Mako,Kabuto, Chizuko,Kabuto, Kuninobu
, p. 7276 - 7277 (2007/10/03)
Reactions of (η5-C5Me4R)(CO)2(MeCN)WMe (R = Me, Et) with HPh2SiC≡CtBu gave the novel alkynyl-bridged W-Si complexes, (η5-C5Me4R)(CO)2W(μ-η1
