85539-65-7Relevant academic research and scientific papers
New synthesis of heterocycles by use of palladium catalyzed cycli zation of α-haloamide with internal double bond
Mori, Miwako,Kanda, Nana,Oda, Izumi,Ban, Yoshio
, p. 5465 - 5474 (2007/10/02)
α-Haloamide having internal double bond was allowed to react with a catalytic amount of Pd(PPh3)4 in the presence of base to produce a cyclized product in a fairly good yield possibly through the intermediate of -alkylmetal complex. By use of this method, five and six membered lactams, pyrrolizidine and quinolizidine derivatives were synthesized in fairly good yields.
CYCLIZATION OF α-HALOAMIDE WITH INTERNAL DOUBLE BOND BY USE OF THE LOW-VALENT METAL COMPLEX
Mori, Miwako,Oda, Izumi,Ban, Yoshio
, p. 5315 - 5318 (2007/10/02)
The α-haloamide having internal double bond was allowed to react with a catalytic amount of Pd(PPh3)4 in the presence of proton sponge to produce a cyclized product in a fairly good yield possibly through the intermediation of ?-alkylmetal complex althoug
